Illinois Administrative Code (Last Updated: March 27, 2024) |
TITLE8. AGRICULTURE AND ANIMALS |
PART259. AGRICHEMICAL FACILITY RESPONSE ACTION PROGRAM |
SUBPARTE. NOTICE OF CLOSURE AND RECORDING REQUIREMENTS |
§259.APPENDIX E. Pesticide Organic Carbon Partition Coefficients and Henry's Law Constants
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Pesticide Name
CAS No.a
Organic Carbon
Partition
Coefficients
Koc (L/kg)b
Henry's Law Constant
H' (unitless)c
acetochlor
34256-82-1
952d
9.14E-07f
acifluorfen sodium
62476-59-9
113
8.10E-13
alachlor
15972-60-8
124
1.32E-06
aldicarb
116-06-3
26
5.07E-09
aldrin
309-00-2
17500
1.65E-02
atrazine
1912-24-9
147
1.01E-07
bentazon sodium
50723-80-3
35
4.63E-14
bromacil
314-40-9
15h
4.57E-09
bromoxynil(o)
1689-99-2
190
1.31E-03
butylate
2008-41-5
304
3.46E-03
carbofuran
1563-66-2
46
2.10E-08
chlordane
57-74-9
60000
3.86E-03
chlorimuron-ethyl
90982-32-4
91h
7.48E-14
chlorpyrifos
2921-88-2
9930
3.02E-04
cyanazine
21725-46-2
218
1.34E-10
2,4-D
94-75-7
48
7.35E-11
4,4'-DDD
72-54-8
231000
3.64E-04
4,4'-DDE
72-55-9
883000
4.15E-03
4,4'-DDT
50-29-3
921000h
3.65E-04
diazinon
333-41-5
1520
2.90E-05
dicamba
1918-00-9
13
1.79E-08
dieldrin
60-57-1
12000
2.65E-05
dimethoate
60-51-5
20
5.61E-10
dinoseb
88-85-7
30g
2.44E-07
disulfoton
298-04-4
1345
6.68E-05
endosulfan
115-29-7
12400
1.19E-05
endothall
145-73-3
85
1.56E-14i
endrin
72-20-8
10000
5.99E-05
EPTC
759-94-4
223
6.56E-04
glyphosate
1071-83-6
2100
5.732-11
HCH-alpha
319-84-6
5440d
3.53E-04e
heptachlor
76-44-8
24000
1.43E-01
heptachlor epoxide
1024-57-3
78600d
2.05E-03e
lindane
58-89-9
1355
7.42E-05
linuron
330-55-2
496
2.56E-07
malathion
121-75-5
1200
4.64E-07
methoxychlor
72-43-5
76000
4.80E-04i
metolachlor
51218-45-2
70
9.91E-07
metribuzin
21087-64-9
52
1.48E-09
parathion, ethyl
56-38-2
7660
9.57E-06
parathion, methyl
298-00-0
6300
3.88E-07
pendimethalin
40487-42-1
12400
4.98E-04
permethrin
52645-53-1
39300
7.68E-05
phorate
298-02-2
1057
4.07E-04
simazine
122-34-9
140
3.96E-08
2,4,5-TP
93-72-1
5440d
2.04E-06e
terbufos
13071-79-9
650
1.09E-03
toxaphene
8001-35-2
100000
2.97E-05
trifluralin
1582-09-8
7200
6.21E-03
Notes:
a Chemical Abstract Service (CAS).
b Selected values from U.S. Department of Agriculture, Agriculture Research Service, Pesticide Properties Database (PPD), Alternate Crops & Systems Laboratory, Beltsville, Maryland, http://wizard.arsusda.gov/acsl/ppdb3.html, unless otherwise noted.
c H' = KH as atm-m3/mol {vapor pressure x molecular weight / solubility in water} x {R (gas constant) x T (temperature as degrees Kelvin)} = KH x 41 at 25° C. Values from the ARS Pesticide Properties Database (PPD), unless otherwise noted.
d Koc = 10((0.983 x log Kow) + 0.00028), log Kow linear relationship with Koc by Di Toro, 1985 (Technical Background Document, p. 140, incorporated by reference at Section 259.150), log Kow values from Syracuse Research Corporation, Physical Properties Database (PHYSPROP), http://esc.syrres.com/interkow/physprop.htm.
e Estimated KH values using data from the SRC Physical Properties Database (PHYSPROP) then converted to H' as noted in c above.
f KH values from the SRC Physical Properties Database (PHYSPROP) then converted to H' as noted in c above.
g Low Koc based on anionic nature (high solubility, low vapor pressure and above pH 5).
h Mean of values listed in ARS Pesticide Properties Database (PPD).
i Estimated using vapor pressure from SRC Physical Properties Database (PHYSPROP).
(Source: Amended at 32 Ill. Reg. 1308, effective January 21, 2008)